The first permanent photograph (later accidentally destroyed) was an image produced in 1826 by the French inventor Joseph Nicéphore Niépce. His photographs were produced on a polished pewter plate covered with a petroleum derivative called bitumen of Judea. Bitumen hardens with exposure to light. The unhardened material may then be washed away and the metal plate polished, rendering a negative image which then may be coated with ink and impressed upon paper, producing a print. Niépce then began experimenting with iron compounds based on a Johann Heinrich Schultz discovery in 1724 that a iron and chalk mixture darkens when exposed to light.
n partnership, Niépce (in Chalon-sur-Saône) and Louis Daguerre (in Paris) refined the existing silver process.[6] In 1833 Niépce died of a stroke, leaving his notes to Daguerre. While he had no scientific background, Daguerre made two pivotal contributions to the process. He discovered that exposing the silver first to iodine vapour before exposure to light, and then to mercury fumes after the photograph was taken, could form a latent image. Bathing the plate in a salt bath then fixes the image. On January 7, 1839 Daguerre announced that he had invented a process using silver on a copper plate called the daguerreotype.The French government bought the patent and immediately made it public domain.
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